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Syllabus
Fundamentals of Chemistry and Matter
What Chemistry Studies
Units, Measurement and Significant Figures
Matter, Properties and States
Energy and Changes of State
Elements, Compounds and Mixtures
Laws of Chemical Combination
Check Yourself: Fundamentals of Chemistry and Matter
The Atom: Structure, Mass and the Mole
Discovery of the Subatomic Particles
Rutherford and the Nuclear Atom
Atomic Number, Mass Number, Isotopes and Ions
Atomic Mass and Mass Spectrometry
The Mole, Molar Mass and Avogadro's Number
Chemical Formulas: Empirical and Molecular
Check Yourself: The Atom
Quantum Mechanics and Electronic Structure
Electromagnetic Radiation as a Wave
Failures of Classical Physics
Black-Body Radiation and Planck
The Photoelectric Effect and Photons
Atomic Line Spectra
The Bohr Atom
Wave-Particle Duality and Uncertainty
de Broglie Wavelength
Heisenberg Uncertainty Principle
Schroedinger Equation and Atomic Orbitals
Quantum Numbers
Shapes of s, p, d and f Orbitals
Electron Spin
Polyelectronic Atoms and Electron Configuration
Orbital Energies: Zeff, Shielding, Penetration
Pauli, Hund and Aufbau: Writing Configurations
Check Yourself: Quantum Mechanics and Electronic Structure
The Periodic Table and Periodic Properties
History and Organisation of the Table
Metals, Non-metals and Metalloids
Atomic and Ionic Radius
Ionisation Energy and Electron Affinity
Summary of Trends and Ion Formation
Check Yourself: The Periodic Table
The Chemical Bond
Why Atoms Bond and the Three Bond Types
The Ionic Bond
Formation and the Born-Haber Cycle
Lattice Energy and Ionic Crystals
The Covalent Bond
Lewis Structures and the Octet Rule
Bond Order, Length and Energy
Exceptions to the Octet Rule
Molecular and Covalent Solids
Electronegativity and Bond Polarity
Molecular Geometry: VSEPR
Electron-Pair Geometries
Lone Pairs and Real Molecular Shapes
Molecular Dipole Moment
The Metallic Bond and Band Theory
Intermolecular Forces
Ion-Dipole and Dipole-Dipole Forces
The Hydrogen Bond
Induced-Dipole and London Forces
Check Yourself: The Chemical Bond
Valence Bond and Molecular Orbital Theories
Valence Bond Theory: Sigma and Pi Bonds
Hybridisation
sp, sp2, sp3 and Expanded Hybrids
Hybridisation of Carbon, Nitrogen and Oxygen
Molecular Orbital Theory
Bonding and Antibonding Orbitals
Bond Order and Homonuclear Diatomic Molecules
Check Yourself: Valence Bond and Molecular Orbital Theories
The Gaseous State
States of Aggregation and the Kinetic Theory of Gases
Pressure and Its Measurement
The Gas Laws
Boyle's Law
Charles's and Gay-Lussac's Laws
Avogadro's Law and Molar Volume
The Ideal Gas Equation
Real Gases and the van der Waals Equation
Gas Mixtures and Dalton's Law
Vapour Pressure
Check Yourself: The Gaseous State
Oxidation Numbers and Inorganic Nomenclature
Oxidation Numbers
Binary Compounds: Hydrides, Oxides and Binary Salts
Ternary Compounds: Hydroxides, Oxyacids and Oxysalts
Check Yourself: Oxidation Numbers and Nomenclature
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